课程介绍

 

　　Thismoduleexploresthermodynamicdefinitions,thezerothlawofthermodynamicsandtemperature,thefirstlawofthermodynamicsandenthalpy,reversibleexpansion,andheatcapacity.

 

　　课程目录

 

　　ThermodynamicsI

 

　　1.1.1Introduction

 

　　1.1.2ThermodynamicDefinitions

 

　　1.2.1TheZerothLawofThermodynamicsandTemperature

 

　　1.2.2TheFirstLawofThermodynamicsandEnthalpy

 

　　1.3.1ReversibleExpansion

 

　　1.3.2HeatCapacity

 

　　1.4.1ThermodynamicsIRecap

 

　　7.QuantumChemistryI

 

　　7.1.1IntroductiontoQuantumChemistrybyDr.PatrickO'Malley

 

　　7.4.2NormalisationoftheWavefunction

 

　　7.4.1Born'sInterpretationoftheWavefunction

 

　　7.3.1TheFreeParticle&theParticleinaBox

 

　　7.2.2TheSchr?dingerEquation

 

　　7.2,1Heisenberg'sUncertaintyPrinciple

 

　　7.1.5WaveNatureofMatter

 

　　7.1.4ParticleNatureofLight-Example

 

　　7.1.3ParticleNatureofLight

 

　　7.1.2Planck'sQuantumofEnergy

 

　　7.4.3ParticleinaBoxApplicationtoPolyeneElectronicSpectra

 

　　6.VirtualLab2Kinetics

 

　　6.1.1IntroductiontoExperiment

 

　　6.1.2GasBuretteExperiment

 

　　6.1.3ExperimentExtraData

 

　　6.2,1Lab2Feedback

 

　　5.ChemicalKineticsII

 

　　5.1.1ComplexReactions_Equilibria

 

　　5.2.1ComplexReactions_Equilibria

 

　　5.2.2ComplexReactions_Consecutivereactions(Rate-DeterminingStep)

 

　　5.3.1Steady-StateApproximation

 

　　5.4.1UsingtheSteadyStateApproximation(LindemannMechanism)

 

　　5.4.2Usingthesteadystateapproximation(ChainReactions)

 

　　5.5.1Catalysis

 

　　5.6.1ChemicalKineticsRecap

 

　　4.ChemicalKineticsI

 

　　4.1.1IntroductiontoChemicalKineticsI

 

　　4.1.2RateofReaction

 

　　4.1.3StoichiometryandOrder

 

　　4.1.4ZeroOrderReactions

 

　　4.2.1FirstOrderReactions

 

　　4.2.2SecondOrderReactions

 

　　4.3.1DeterminationofReactionOrder

 

　　4.3.2ExperimentalDeterminationofReactionOrder

 

　　4.4.1EffectofTemperatureonReactionRate

 

　　3.VirtualLab1Thermodynamics

 

　　3.1.1IntroductiontoExperiment

 

　　3.1.2CalorimeterExperiment

 

　　2.ThermodynamicsII

 

　　2.1.1ThermodynamicsIIIntroduction

 

　　2.2.1TheSecondLawofThermodynamicsandEntropy

 

　　2.2.2TheSecondLawofThermodynamicsandEquilibrium

 

　　2.3.1TheSecondLawofThermodynamicsandSpontaneity

 

　　2.3.2TheThirdLawofThermodynamicsandAbsoluteEntropy

 

　　2.3.3Hess'Law

 

　　2.4.1ThermodynamicsRecap

 

　　8VirtualLab3:ParticleinaBox

 

　　8.1ParticleinaBoxIntroduction

 

　　9QuantumChemistryII

 

　　9.1IntroductiontoQuantumChemistryIbyDr.PatrickO'Malley

 

　　9.2IntroductiontoHydrogenicAtoms

 

　　9.3HydrogenicAtomQuantumNumbers

 

　　9.4RadialSolutionsforHydrogenicAtoms

 

　　9.5AngularSolutionsforHydrogenicAtoms

 

　　9.6InterpretationofHydrogenicAtomSolutions

 

　　9.7EnergylevelsforHydrogenicAtoms

 

　　10VirtualLab4:HydrogenEmissionSpectroscopy

 

　　10.1HydrogenEmissionIntroduction

 

　　10.2QuantumLabFeedback